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Amino Acids  >  Unusual Amino Acids  >  Azide and Alkyne containing Amino Acids  >>  Boc-L-propargylglycine•DCHA

Product Name Boc - L - propargylglycine•DCHA
CAS 63039-48-5
Size 5 g
Catalog # AS-26264-B5
US$ $583
Description

An unusual amino acid used in Solid Phase Peptide Synthesis (SPPS) as: A) a precursor to the tritium-induced Norvaline peptides,1 B) in the synthesis of branched peptides using a palladium-catalyzed coupling reaction,2 and C) as a reagent in the dual-catalyst Sonogashira coupling reaction.3

Detailed Information Datasheet
Material Safety Data Sheets (MSDS)
Flyer
Storage 4°C
References 1. Eberle, A. N.; Zeller, A. Tritiation of Peptides to High Specific Radioactivity. Part 1. Synthesis and Biological Properties of [13-(3H4)Norvaline]-α-MSH and of [2,23-Bis((3H2)tyrosine)]ACTH(1-24). Helvetica Chim. Acta. 1985 (68) 1880-1892.
2. Crisp, G. T.; Robertson, T. A. Palladium-catalyzed coupling of a propargylglycinededrivative. Tetrahedron. 1992 (48) 3239-3250.
3. Sonogashira, K.; Tohda, Y.; Haghiara, N. A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes, and bromopyridines.Tetrahedron Lett.,1975 (16) 4467-4470.
Molecular Weight 213.2•181.3
Molecular Formula C10H15NO4
     
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